Complex Nanoscale Cage Clusters Built from Uranyl Polyhedra and Phosphate Tetrahedra

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• 作者：Daniel K. Unruh ; Jie Ling ; Jie Qiu ; Laura Pressprich ; Melissa Baranay ; Matthew Ward ; Peter C. Burns
• 刊名：Inorganic Chemistry
• 出版年：2011
• 出版时间：June 20, 2011
• 年：2011
• 卷：50
• 期：12
• 页码：5509-5516
• 全文大小：1038K
• 年卷期：v.50,no.12(June 20, 2011)
• ISSN：1520-510X

文摘

Five cage clusters that self-assemble in alkaline aqueous solution have been isolated and characterized. Each is built from uranyl hexagonal bipyramids with two or three equatorial edges occupied by peroxide, and three also contain phosphate tetrahedra. These clusters contain 30 uranyl polyhedra; 30 uranyl polyhedra and six pyrophosphate groups; 30 uranyl polyhedra, 12 pyrophosphate groups, and one phosphate tetrahedron; 42 uranyl polyhedra; and 40 uranyl polyhedra and three pyrophosphate groups. These clusters present complex topologies as well as a range of compositions, sizes, and charges. Two adopt fullerene topologies, and the others contain combinations of topological squares, pentagons, and hexagons. An analysis of possible topologies further indicates that higher-symmetry topologies are favored.