Pyridine Adducts of Nickel(II) Xanthates as Single-Source Precursors for the Aerosol-Assisted Chemical Vapor Deposition of Nickel Sulfide

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• 作者：Naveed Alam ; Michael S. Hill ; Gabriele Kociok-Kö ; hn ; Matthias Zeller ; Muhammad Mazhar ; Kieran C. Molloy
• 刊名：Chemistry of Materials
• 出版年：2008
• 出版时间：October 14, 2008
• 年：2008
• 卷：20
• 期：19
• 页码：6157-6162
• 全文大小：261K
• 年卷期：v.20,no.19(October 14, 2008)
• ISSN：1520-5002

文摘

Compounds of the type [Ni(S₂COⁿBu)₂·(py)₂] (py = pyridine derivative) have been synthesized and studied as single-source precursors for the fabrication of phase-pure thin films of rhombohedral (Millerite) NiS by aerosol-assisted chemical vapor deposition. The films have been characterized by XRD, SEM, EDX, and AFM and have been found to display a substrate-dependent morphology that is effectively independent of the precise identity of the precursor complex, regardless of minor variations in thermal stability.