Organometallic Platinum(II) and Palladium(II) Polymers Containing 2,6-Diethynyl-4-nitroaniline Bridging Spacer and Related Dinuclear Model Complexes
详细信息 查看全文
- 作者：Rosaria D'Amato ; Ilaria Fratoddi ; Alberto Cappotto ; Patrizia Altamura ; Maurizio Delfini ; Cristiano Bianchetti ; Adriana Bolasco ; Giovanni Polzonetti ; and Maria V. Russo
- 刊名：Organometallics
- 出版年：2004
- 出版时间：June 7, 2004
- 年：2004
- 卷：23
- 期：12
- 页码：2860 - 2869
- 全文大小：150K
- 年卷期：v.23,no.12(June 7, 2004)
- ISSN：1520-6041
文摘
The metal-carbon coupling in dehydrohalogenation conditions between Pt(II) or Pd(II)square planar bisphosphine dichloride complexes and 2,6-diethynyl-4-nitroaniline (DENA)yielded organometallic polymers, i.e., -[M(PTol3)2(-C
C-R-CC-)]n- with R = p-NH2C6H2NO2 and M = Pt(II) or Pd(II). Dinuclear platinum complexes were also synthesized asgeometrical models. The polymers and complexes were fully characterized by means ofspectroscopic techniques. Accurate investigations with 2D nuclear magnetic resonance (NMR)spectroscopy were used to define the chemical and spatial structure of the polymeric chainsas a helical conformation for both Pt(II)- and Pd(II)-based organometallic polymers. Opticalabsorption studies and X-ray photoelectron spectroscopy measurements revealed the extentof conjugation and the nature of the ending groups.
C-R-CC-)]n- with R = p-NH2C6H2NO2 and M = Pt(II) or Pd(II). Dinuclear platinum complexes were also synthesized asgeometrical models. The polymers and complexes were fully characterized by means ofspectroscopic techniques. Accurate investigations with 2D nuclear magnetic resonance (NMR)spectroscopy were used to define the chemical and spatial structure of the polymeric chainsas a helical conformation for both Pt(II)- and Pd(II)-based organometallic polymers. Opticalabsorption studies and X-ray photoelectron spectroscopy measurements revealed the extentof conjugation and the nature of the ending groups.