Synthesis and Characterization of a 1-D Porous Barium Carboxylate Coordination Polymer, [Ba(HBTB)] (H3BTB = Benzene-1,3,5-trisbenzoic Acid)

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• 作者：Maw Lin Foo ; Satoshi Horike ; Susumu Kitagawa
• 刊名：Inorganic Chemistry
• 出版年：2011
• 出版时间：December 5, 2011
• 年：2011
• 卷：50
• 期：23
• 页码：11853-11855
• 全文大小：215K
• 年卷期：v.50,no.23(December 5, 2011)
• ISSN：1520-510X

文摘

The synthesis and characterization of [Ba(HBTB)] is reported. This is the first porous framework synthesized with barium using carboxylate ligands. The framework has robust microporous character (Langmuir surface area of 879 m² g^鈥?) and possesses unsaturated metal sites when fully desolvated.