Experiments and Modeling of Uranium Uptake by Amidoxime-Based Adsorbent in the Presence of Other Ions in Simulated Seawater

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• 作者：A. P. Ladshaw ; S. Das ; W.-P. Liao ; S. Yiacoumi ; C. J. Janke ; R. T. Mayes ; S. Dai ; C. Tsouris
• 刊名：Industrial & Engineering Chemistry Research
• 出版年：2016
• 出版时间：April 20, 2016
• 年：2016
• 卷：55
• 期：15
• 页码：4241-4248
• 全文大小：463K
• 年卷期：0
• ISSN：1520-5045

文摘

Seawater contains uranium at an average concentration of 3.3 ppb, as well as a variety of other ions at either overwhelmingly higher or similar concentrations, which complicate the recovery of uranium. This report describes an investigation of the effects of various factors such as uranium speciation and presence of salts including sodium, calcium, magnesium, and bicarbonate, as well as trace elements such as vanadium on uranium adsorption kinetics in laboratory experiments. Adsorption models are also developed to describe the experimental data of uranium extraction from seawater. Results show that the presence of calcium and magnesium significantly slows down the uranium adsorption kinetics. Vanadium can replace uranium from amidoxime-based adsorbent in the presence of sodium in the solution. Results also show that bicarbonate in the solution strongly competes with amidoxime for binding uranium, and thus slows down the uranium adsorption kinetics. Developed on the basis of the experimental findings, the model is capable of describing the effects of pH, ionic strength, temperature, and concentration of various species. The results of this work are useful in the understanding of the important factors that control the adsorbent capacity and kinetics of uranium uptake by amidoxime-based adsorbents.