Mechanically Strong, Flexible Polyimide Aerogels Cross-Linked with Aromatic Triamine

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• 作者：Mary Ann B. Meador ; Ericka J. Malow ; Rebecca Silva ; Sarah Wright ; Derek Quade ; Stephanie L. Vivod ; Haiquan Guo ; Jiao Guo ; Miko Cakmak
• 刊名：ACS Applied Materials & Interfaces
• 出版年：2012
• 出版时间：February 22, 2012
• 年：2012
• 卷：4
• 期：2
• 页码：536-544
• 全文大小：513K
• 年卷期：v.4,no.2(February 22, 2012)
• ISSN：1944-8252

文摘

Polyimide gels are produced by cross-linking anhydride capped polyamic acid oligomers with aromatic triamine in solution and chemically imidizing. The gels are then supercritically dried to form nanoporous polyimide aerogels with densities as low as 0.14 g/cm³ and surface areas as high as 512 m²/g. To understand the effect of the polyimide backbone on properties, aerogels from several combinations of diamine and dianhydride, and formulated oligomer chain length are examined. Formulations made from 2,2鈥?dimethylbenzidine as the diamine shrink the least but have among the highest compressive modulus. Formulations made using 4,4鈥?oxydianiline or 2,2鈥瞕imethylbenzidine can be fabricated into continuous thin films using a roll to roll casting process. The films are flexible enough to be rolled or folded back on themselves and recover completely without cracking or flaking, and have tensile strengths of 4鈥? MPa. Finally, the highest onset of decomposition (above 600 掳C) of the polyimide aerogels was obtained using p-phenylene diamine as the backbone diamine with either dianhydride studied. All of the aerogels are suitable candidates for high-temperature insulation with glass transition temperatures ranging from 270鈥?40 掳C and onsets of decomposition from 460鈥?10 掳C.<br>

Keywords:

aerogel; polyimide; cross-linking; nanoporous materials; high-temperature insulation