The photo-oxidation behavior of three different polymers鈥攏amely, poly(3-hexylthiophene) (P3HT), poly[2,6-(4,4-bis(2-ethylhexyl)-4H-
cy
clopenta[2,1-b;3,4-b鈥瞉dithiophene)-
alt-4,7-(2,1,3-benzothiadiazole)] (C-PCPDTBT), and poly[2,6-(4,4-bis(2-ethylhexyl)dithieno[3,2-b:2鈥?3鈥?d]silole)-
alt-4,7-(2,1,3-benzothiadiazole)] (Si-PCPDTBT)鈥攊s investigated in neat polymer films and in blends with [6,6]-phenyl-C
61-butyri
c a
cid methyl ester (PCBM) for different polymer:PCBM ratios. PCBM is shown to have both stabilizing and destabilizing effe
cts, the extent of whi
ch is dependent on the type of polymer with whi
ch it is blended. S
creening of the polymer from in
cident light by PCBM turns out to play an only minor role in the stabilization of P3HT. Quen
ching of the polymer ex
cited states is also not a signifi
cant stabilization me
chanism, as demonstrated by the
comparison of the redu
ction of photo-oxidation rates to the extent of photolumines
cen
ce quen
ching by PCBM and 2,7-dinitrofluorenone (DNF). Photoindu
ced absorption spe
ctros
copy reveals that the enhan
ced degradation of C-PCPDTBT in blend films with PCBM
correlates with the population of the polymer triplet state via the polymer:PCBM
charge-transfer state.
Keywords:
cs.org/action/doSearch?action=search&searchText=organic+solar+cells&qsSearchArea=searchText">organic solar cells; cs.org/action/doSearch?action=search&searchText=stability&qsSearchArea=searchText">stability; cs.org/action/doSearch?action=search&searchText=fullerenes&qsSearchArea=searchText">fullerenes; cs.org/action/doSearch?action=search&searchText=charge+transfer+states&qsSearchArea=searchText">charge transfer states; cs.org/action/doSearch?action=search&searchText=triplet+population&qsSearchArea=searchText">triplet population