A Career in Catalysis: Masakatsu Shibasaki
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  • 作者:Naoya Kumagai ; Motomu Kanai ; Hiroaki Sasai
  • 刊名:ACS Catalysis
  • 出版年:2016
  • 出版时间:July 1, 2016
  • 年:2016
  • 卷:6
  • 期:7
  • 页码:4699-4709
  • 全文大小:993K
  • 年卷期:0
  • ISSN:2155-5435
文摘
Professor Masakatsu Shibasaki’s distinguished scientific accomplishments in the field of asymmetric catalysis are compiled here with particular emphasis on multimetallic cooperative catalysis. In 1992, he discovered revolutionary multimetallic chiral complexes composed of a rare earth metal, alkaline metals, and 1,1′-binaphthyl-2-binaphthols (BINOLs) that promoted a number of enantioselective reactions in a highly efficient and stereoselective manner. This finding resulted in chiral multimetallic catalysts that have significantly advanced the field of enantioselective catalysis.

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