Kinetic Resolution in Asymmetric Epoxidation using Iminium Salt Catalysis
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- 作者：Philip C. Bulman Page ; Louise F. Appleby ; Yohan Chan ; David P. Day ; Benjamin R. Buckley ; Alexandra M. Z. Slawin ; Steven M. Allin ; Michael J. McKenzie
- 刊名：The Journal of Organic Chemistry
- 出版年：2013
- 出版时间：August 16, 2013
- 年：2013
- 卷：78
- 期：16
- 页码：8074-8082
- 全文大小：385K
- 年卷期：v.78,no.16(August 16, 2013)
- ISSN：1520-6904
文摘
The first reported examples of kinetic resolution in epoxidation reactions using iminium salt catalysis are described, providing up to 99% ee in the epoxidation of racemic cis-chromenes.