Addressable Carbene Anchors for Gold Surfaces

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• 作者：Aleksandr V. Zhukhovitskiy ; Michael G. Mavros ; Troy Van Voorhis ; Jeremiah A. Johnson
• 刊名：The Journal of the American Chemical Society
• 出版年：2013
• 出版时间：May 22, 2013
• 年：2013
• 卷：135
• 期：20
• 页码：7418-7421
• 全文大小：392K
• 年卷期：v.135,no.20(May 22, 2013)
• ISSN：1520-5126

文摘

New strategies to access functional monolayers could augment current surface modification methods. Here we present addressable N-heterocyclic carbene (ANHC) anchors for gold surfaces. A suite of experimental and theoretical methods was used to characterize ANHC monolayers. We demonstrate grafting of highly fluorinated polymers from surface-bound ANHCs. This work establishes ANHCs as viable anchors for gold surfaces.