Self-Assembly of a 3-D Triply Interlocked Chiral [2]Catenane

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• 作者：Aleema Westcott ; Julie Fisher ; Lindsay P. Harding ; Pierre Rizkallah ; Michaele J. Hardie
• 刊名：Journal of the American Chemical Society
• 出版年：2008
• 出版时间：March 12, 2008
• 年：2008
• 卷：130
• 期：10
• 页码：2950 - 2951
• 全文大小：131K
• 年卷期：v.130,no.10(March 12, 2008)
• ISSN：1520-5126

文摘

A tripodal cyclotriveratrylene-based ligand with chelating 2,2'-bipyridine arms self-assembles with either Zn(NO₃)₂ or Co(NO₃)₂ to give 3-D trigonal bipyramidal [M₃L₂] cage assemblies. These cages triply interlock forming [2]catenane species that have been characterized by mass spectrometry and, in the case of the Zn(II) complex, by X-ray crystallography.