Electrochemical Quartz Crystal Microbalance (EQCM) Studies of Ions and Solvents Insertion into Highly Porous Activated Carbons
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- 作者：Mikhael D. Levi ; Naomi Levy ; Sergey Sigalov ; Gregory Salitra ; Doron Aurbach ; Joachim Maier
- 刊名：Journal of the American Chemical Society
- 出版年：2010
- 出版时间：September 29, 2010
- 年：2010
- 卷：132
- 期：38
- 页码：13220-13222
- 全文大小：157K
- 年卷期：v.132,no.38(September 29, 2010)
- ISSN：1520-5126
文摘
Electrochemical quartz crystal microbalance (EQCM) technique provides a direct assessment to the behavior of electroadsorbed ions and solvent molecules confined in micropores of activated carbon electrodes in contact with practically important aprotic electrolyte solutions. The estimated value of the solvation number equal to 3 is evident for a partial desolvation of Li+ cations when adsorbed in carbon micropores.