Metathesis Reaction-Induced Significant Improvement in Hydrogen Storage Properties of the KF-Added Mg(NH2)2鈥?LiH System
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- 作者：Yongfeng Liu ; Chao Li ; Bo Li ; Mingxia Gao ; Hongge Pan
- 刊名：The Journal of Physical Chemistry C
- 出版年：2013
- 出版时间：January 17, 2013
- 年：2013
- 卷：117
- 期：2
- 页码：866-875
- 全文大小：577K
- 年卷期：v.117,no.2(January 17, 2013)
- ISSN：1932-7455
文摘
The hydrogen storage properties and mechanisms of the Mg(NH2)2鈥?LiH system with potassium halides (KF, KCl, KBr, and KI) were investigated and discussed. The results show that the KF-added sample exhibits superior hydrogen storage properties as 5.0 wt % of hydrogen can be reversibly stored in the 0.08KF-added sample via a two-stage reaction with an onset dehydrogenation temperature of 80 掳C. However, hydrogen storage behaviors of the samples with KCl, KBr, and KI remain almost unchanged. The fact that KF can readily react with LiH to convert to KH and LiF due to the favorable thermodynamics during ball milling should be the primary reason for its significant effects, as the presence of KH provides a synergetic thermodynamic and kinetic destabilization in the hydrogen storage reaction of the Mg(NH2)2鈥?LiH system by declining the activation energy of the first-step dehydrogenation as a catalyst and reducing the desorption enthalpy change of the second step as a reactant. The understanding on the role played by KF sheds light on how to further decrease the operating temperature and enhance the hydrogen storage kinetics of the metal鈥揘鈥揌 system.