Hydrogenation of Benzoic Acid and Derivatives over Pd Nanoparticles Supported on N-Doped Carbon Derived from Glucosamine Hydrochloride
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- 作者：Xuan Xu ; Minghui Tang ; Mingming Li ; Haoran Li ; Yong Wang
- 刊名：ACS Catalysis
- 出版年：2014
- 出版时间：September 5, 2014
- 年：2014
- 卷：4
- 期：9
- 页码：3132-3135
- 全文大小：292K
- ISSN：2155-5435
文摘
A novel N-doped carbon (CN) was prepared by the hydrothermal method using glucosamine hydrochloride as both carbon and nitrogen precursor, followed by a postsynthesis heat treatment. Pd@CN exhibited 9 times higher activity compared to that of commercial Pd@AC on hydrogenation of benzoic acid to cyclohexanecarboxylic acid. The influence of solvent and substituent were also investigated. Besides, the hydrogenations of various benzoic acids have been carried out over Pd@CN.