Pd/TiO2 Washcoated Cordierite Minimonoliths for Hydrodechlorination of Light Organochlorinated Compounds
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- 作者：Carlos A. Gonzá ; lez ; Alba N. Ardila ; C. Montes de Correa ; Miguel A. Martí ; nez ; Gustavo Fuentes-Zurita
- 刊名：Industrial & Engineering Chemistry Research
- 出版年：2007
- 出版时间：November 21, 2007
- 年：2007
- 卷：46
- 期：24
- 页码：7961 - 7969
- 全文大小：401K
- 年卷期：v.46,no.24(November 21, 2007)
- ISSN：1520-5045
文摘
Pd over TiO2 (sol-gel and Hombikat uv-100) slurries with and without binders have been deposited onsquare-channel cordierite honeycombs, and vibration, heat, and abrasion resistance of washcoated minimonolithshave been evaluated. Activity tests were carried out in a microreactor operated at differential conditions.Fresh and used catalyst samples were characterized by elemental analysis, XRD, BET, H2-chemisorption,H2-TPR, NH3-TPD, UV-vis, and SEM in order to assess not only the properties but also the homogeneityof catalyst layers. The results show that washcoat loading and catalytic performance are affected by the kindof binder used in the slurry. Washcoat differences are also found regarding vibration, heat, and abrasionresistance.