A Self-Assembled, Decameric Water Cluster Stabilized by a Cyano-Bridged Copper(II) Complex

详细信息    查看全文

• 作者：Uday Mukhopadhyay and Ivan Bernal
• 刊名：Crystal Growth & Design
• 出版年：2006
• 出版时间：February 2006
• 年：2006
• 卷：6
• 期：2
• 页码：363 - 365
• 全文大小：128K
• 年卷期：v.6,no.2(February 2006)
• ISSN：1528-7505

文摘

A self-assembled, decameric water cluster stabilized by a cyano-bridged copper(II) complex was characterized by X-raydiffraction studies, FTIR, and thermogravimetric (TG) and differential scanning calorimetric (DSC) analyses. Every water cluster is connectedstrongly, via hydrogen bonds, to four cyano nitrogens of a [Fe(CN)₆]^4- anion. The complex water rings are stable indefinitely at roomtemperature, and when thermally decomposed, the water loss is irreversible.