Highly Selective CO2 Adsorption Accompanied with Low-Energy Regeneration in a Two-Dimensional Cu(II) Porous Coordination Polymer with Inorganic Fluorinated PF6鈥?/sup> Anions

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• 作者：Shin-ichiro Noro ; Yuh Hijikata ; Munehiro Inukai ; Tomohiro Fukushima ; Satoshi Horike ; Masakazu Higuchi ; Susumu Kitagawa ; Tomoyuki Akutagawa ; Takayoshi Nakamura
• 刊名：Inorganic Chemistry
• 出版年：2013
• 出版时间：January 7, 2013
• 年：2013
• 卷：52
• 期：1
• 页码：280-285
• 全文大小：358K
• 年卷期：v.52,no.1(January 7, 2013)
• ISSN：1520-510X

文摘

High selectivity and low-energy regeneration for adsorption of CO₂ gas were achieved concurrently in a two-dimensional Cu(II) porous coordination polymer, [Cu(PF₆)₂(4,4鈥?bpy)₂]_n (4,4鈥?b>-bpy = 4,4鈥?b>-bipyridine), containing inorganic fluorinated PF₆^{鈥?/sup> anions that can act as moderate interaction sites for CO₂ molecules.}