Postsynthesis Modification of a Porous Coordination Polymer by LiCl To Enhance H+ Transport

详细信息    查看全文

• 作者：Satoshi Horike ; Yusuke Kamitsubo ; Munehiro Inukai ; Tomohiro Fukushima ; Daiki Umeyama ; Tomoya Itakura ; Susumu Kitagawa
• 刊名：The Journal of the American Chemical Society
• 出版年：2013
• 出版时间：March 27, 2013
• 年：2013
• 卷：135
• 期：12
• 页码：4612-4615
• 全文大小：219K
• 年卷期：v.135,no.12(March 27, 2013)
• ISSN：1520-5126

文摘

A Ca²⁺ porous coordination polymer with 1D channels was functionalized by the postsynthesis addition of LiCl to enhance the H⁺ conductivity. The compound showed over 10^鈥? S cm^鈥? at 25 掳C and 20% relative humidity. Pulse-field gradient NMR elucidated that the fast H⁺ conductivity was achieved by the support of Li⁺ ion movements in the channel.