Solvent-Mediated Room Temperature Synthesis of Highly Crystalline Cu9S5 (Cu1.8S), CuSe, PbS, and PbSe from Their Elements
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- 作者：Prashant Kumar ; Meenakshi Gusain ; Rajamani Nagarajan
- 刊名：Inorganic Chemistry
- 出版年：2012
- 出版时间：August 6, 2012
- 年：2012
- 卷：51
- 期：15
- 页码：7945-7947
- 全文大小：200K
- 年卷期：v.51,no.15(August 6, 2012)
- ISSN：1520-510X
文摘
Highly crystalline Cu9S5 (Cu1.8S), CuSe, PbS, and PbSe are obtained by reacting the elements in 2-mercaptoethanol as the solvent for 24 h at room temperature. The elemental reactions of copper and lead with sulfur in ethylene glycol were successful, yielding CuS and PbS, respectively. Metal sulfide formation was not observed using dimercaptoethane.