Bistable Dynamic Coordination Polymer Showing Reversible Structural and Functional Transformations

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• 作者：Sanjog S. Nagarkar ; Raja Das ; Pankaj Poddar ; Sujit K. Ghosh
• 刊名：Inorganic Chemistry
• 出版年：2012
• 出版时间：August 6, 2012
• 年：2012
• 卷：51
• 期：15
• 页码：8317-8321
• 全文大小：390K
• 年卷期：v.51,no.15(August 6, 2012)
• ISSN：1520-510X

文摘

A bistable dynamic coordination polymer [Ni(pca)(bdc)_0.5(H₂O)₂] having a two-dimensional (2D) zigzag sheet structure is synthesized solvothermally. Topological analysis revealed that the frameworks have an hcb type of uninodal net. The compound exhibits guest specific reversible structural transformations accompanying reversible changes in physical properties driven by inherent flexibility and transformability.