Synthesis and Complexation of a New Tripodal Tetradentate Ligand, a Silyl Ligand Tethered with Three Thioether Moieties

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• 作者：Nobuhiro Takeda ; Daisuke Watanabe ; Tetsu Nakamura ; Masafumi Unno
• 刊名：Organometallics
• 出版年：2010
• 出版时间：July 12, 2010
• 年：2010
• 卷：29
• 期：13
• 页码：2839-2841
• 全文大小：804K
• 年卷期：v.29,no.13(July 12, 2010)
• ISSN：1520-6041

文摘

Iridium(III) and platinum(II) complexes with a new tripodal tetradentate ligand, tris[2-(tert-butylthiomethyl)phenyl]silyl were synthesized. In addition, reaction of tris(2-((tert-butylthio)methyl)phenyl)silane with [PdCl₂(PhCN)₂] resulted in the cleavage of the Si−C bond to give [{Pd[2-(t-BuSCH₂)C₆H₄]}₂(μ-Cl)₂].