Electricity Generation and Pollutant Degradation Using a Novel Biocathode Coupled Photoelectrochemical Cell

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• 作者：Yue Du ; Yujie Feng ; Youpeng Qu ; Jia Liu ; Nanqi Ren ; Hong Liu
• 刊名：Environmental Science & Technology
• 出版年：2014
• 出版时间：July 1, 2014
• 年：2014
• 卷：48
• 期：13
• 页码：7634-7641
• 全文大小：441K
• ISSN：1520-5851

文摘

The photoelectrochemical cell (PEC) is a promising tool for the degradation of organic pollutants and simultaneous electricity recovery, however, current cathode catalysts suffer from high costs and short service lives. Herein, we present a novel biocathode coupled PEC (Bio-PEC) integrating the advantages of photocatalytic anode and biocathode. Electrochemical anodized TiO₂ nanotube arrays fabricated on Ti substrate were used as Bio-PEC anodes. Field-emission scanning electron microscope images revealed that the well-aligned TiO₂ nanotubes had inner diameters of 60鈥?00 nm and wall-thicknesses of about 5 nm. Linear sweep voltammetry presented the pronounced photocurrent output (325 渭A/cm²) under xenon illumination, compared with that under dark conditions. Comparing studies were carried out between the Bio-PEC and PECs with Pt/C cathodes. The results showed that the performance of Pt/C cathodes was closely related with the structure and Pt/C loading amounts of cathodes, while the Bio-PEC achieved similar methyl orange (MO) decoloration rate (0.0120 min^鈥?) and maximum power density (211.32 mW/m²) to the brush cathode PEC with 50 mg Pt/C loading (Brush-PEC, 50 mg). The fill factors of Bio-PEC and Brush-PEC (50 mg) were 39.87% and 43.06%, respectively. The charge transfer resistance of biocathode was 13.10 惟, larger than the brush cathode with 50 mg Pt/C (10.68 惟), but smaller than the brush cathode with 35 mg Pt/C (18.35 惟), indicating the comparable catalytic activity with Pt/C catalyst. The biocathode was more dependent on the nutrient diffusion, such as nitrogen and inorganic carbon, thus resulting in relatively higher diffusion resistance compared to the brush cathode with 50 mg Pt/C loading that yielded similar MO removal and power output. Considering the performance and cost of PEC system, the biocathode was a promising alternative for the Pt/C catalyst.