Exciton Formation at Solid鈥揝olid Interfaces: A Systematic Experimental and ab Initio Study on Compressed MgO Nanopowders
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- 作者：Andreas Sternig ; David Koller ; Nicolas Siedl ; Oliver Diwald ; Keith McKenna
- 刊名：The Journal of Physical Chemistry C
- 出版年：2012
- 出版时间：May 10, 2012
- 年：2012
- 卷：116
- 期：18
- 页码：10103-10112
- 全文大小：557K
- 年卷期：v.116,no.18(May 10, 2012)
- ISSN：1932-7455
文摘
An important and so far neglected class of structural elements affecting the overall properties of metal oxide nanopowders are interfaces between individual nanocrystals. In this work, we show experimentally that these defects inside a powder of compressed MgO nanocubes are subject to photoexcitation in the UV light range. In particular, we identify a so far unobserved photoluminescence emission process at 2.5 eV. First-principles calculations of the optical properties of nanocrystal interfaces provide plausible candidates for both light absorbing and emitting sites, which involve different types of interface features. It was found that edge dislocations that arise from interfaces between nanocube edges and terraces induce a significant electrostatic perturbation of the interfacial electronic states. This leads to exciton generation and luminescence at even lower energies than those related to corners and edges of MgO nanocubes.