Mode-Switching of the Self-Motion of a Camphor Boat Depending on the Diffusion Distance of Camphor Molecules

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• 作者：Nobuhiko J. Suematsu ; Yumihiko Ikura ; Masaharu Nagayama ; Hiroyuki Kitahata ; Nao Kawagishi ; Mai Murakami ; Satoshi Nakata
• 刊名：Journal of Physical Chemistry C
• 出版年：2010
• 出版时间：June 3, 2010
• 年：2010
• 卷：114
• 期：21
• 页码：9876-9882
• 全文大小：225K
• 年卷期：v.114,no.21(June 3, 2010)
• ISSN：1932-7455

文摘

We demonstrated mode-switching of self-motion coupled with diffusion of molecules at a solid/liquid interface. A camphor boat moved spontaneously on water and the mode of self-motion depended on the setup of the boat. When a camphor disk was connected to the center of a larger plastic plate, intermittent motion (alternating between rest and rapid motion) was observed. When the position of the camphor disk was changed from the center to one of its edges, the period of intermittent motion decreased, and intermittent motion changed to continuous motion. The features of this self-motion and mode-switching were qualitatively reproduced by a numerical calculation using a mathematical model that incorporates the distribution of camphor molecules at the solid/liquid interface.