Structure of Silver(I) Complex Prepared from Azobenzenonaphthalenophane, Photochemical Coordination Change of Silver(I) and Silver(I)-Induced Acceleration of Z−E Thermal Isomerizat

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• 作者：Yoshimi Oka ; Nobuyuki Tamaoki
• 刊名：Inorganic Chemistry
• 出版年：2010
• 出版时间：June 7, 2010
• 年：2010
• 卷：49
• 期：11
• 页码：4765-4767
• 全文大小：693K
• 年卷期：v.49,no.11(June 7, 2010)
• ISSN：1520-510X

文摘

A Ag^I complex was prepared from azobenzenonaphthalenophane as a photoreactive multidentate ligand. The coordination of Ag^I was reversibly controlled by photoisomerization of the azobenzene unit, and at the same time, Ag^I accelerated the Z−E thermal isomerization of the azobenzene unit.