Electrochemical Behavior of an Aminotrithioether Ligand: Copper(II)-Mediated Oxidative C-C Bond Formation

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• 作者：Raú ; l Huerta ; Aar&oacute ; n Flores-Figueroa ; Ví ; ctor M. Ugalde-Saldí ; var ; Ivan Castillo
• 刊名：Inorganic Chemistry
• 出版年：2007
• 出版时间：November 12, 2007
• 年：2007
• 卷：46
• 期：23
• 页码：9510 - 9512
• 全文大小：105K
• 年卷期：v.46,no.23(November 12, 2007)
• ISSN：1520-510X

文摘

A neutral aminotrithioether interacts with Cu^I, generating acoordination polymer in the solid state. Electrochemical studiesindicate that the ligand is prone to oxidation by Cu^II, which resultsin a novel C-C bond formation reaction.