The Electronic Spectrum of AuO: A Combined Theoretical and Experimental Study
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- 作者：Leah C. O'Brien ; Anne E. Oberlink ; Bjö ; rn O. Roos
- 刊名：Journal of Physical Chemistry A
- 出版年：2006
- 出版时间：November 2, 2006
- 年：2006
- 卷：110
- 期：43
- 页码：11954 - 11957
- 全文大小：71K
- 年卷期：v.110,no.43(November 2, 2006)
- ISSN：1520-5215
文摘
The near-infrared electronic spectrum of AuO1 has been re-examined in light of the new microwave data onthe v = 0 and v = 1 vibrations of the X2
3/2 state of AuO. The two observed bands in the spectrum, withred-degraded bandheads located at 10726 and 10665 cm-1, have been reanalyzed. New theoretical work onAuO clarifies the electronic structure, and the bands in the infrared are now assigned as the (0,1) and (1,2)bands of the a4
-3/2 - X23/2 transition, respectively.
3/2 state of AuO. The two observed bands in the spectrum, withred-degraded bandheads located at 10726 and 10665 cm-1, have been reanalyzed. New theoretical work onAuO clarifies the electronic structure, and the bands in the infrared are now assigned as the (0,1) and (1,2)bands of the a4-3/2 - X23/2 transition, respectively.