Infinite Dilution Partial Molar Volumes of Aqueous Solutes over Wide Ranges of Conditions

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• 作者：John P. O'Connell ; Andrei V. Sharygin ; and Robert H. Wood
• 刊名：Industrial & Engineering Chemistry Research
• 出版年：1996
• 出版时间：August 1996
• 年：1996
• 卷：35
• 期：8
• 页码：2808 - 2812
• 全文大小：164K
• 年卷期：v.35,no.8(August 1996)
• ISSN：1520-5045

文摘

Data for the partial molar volume at infinite dilution for severalgaseous solutes and H₃BO₃ inwater have been correlated using a generalized Krichevskii parameter.The result is a simplefunction forjournals/iecred/35/i08/eqn/ie950729ue10001.gif"> interms of the water density and compressibility for conditions fromambient to725 K and 40 MPa. The accuracy is much better with only twoparameters than with a previousfive-parameter model.