Incorporation of Dyes into Hydrogen-Bond Networks: The Structures and Properties of Guanidinium Sulfonate Derivatives Containing Ethyl Orange and 4-Aminoazobenzene-4'-sulfonate
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- 作者：Nichola J. Burke ; Andrew D. Burrows ; Mary F. Mahon ; and John E. Warren
- 刊名：Crystal Growth & Design
- 出版年：2006
- 出版时间：February 2006
- 年：2006
- 卷：6
- 期：2
- 页码：546 - 554
- 全文大小：538K
- 年卷期：v.6,no.2(February 2006)
- ISSN：1528-7505
文摘
The ethyl orange-based guanidinium sulfonate (GS) compounds [C(NH2)3][O3SR] (1), [C(NH2)2(NHMe)][O3SR]·MeOH (2), [C(NH2)2(NHEt)][O3SR] (3), and [C(NH2)2(NMe2)][O3SR] (4) (R = C6H4N=NC6H4NEt2) have been prepared andcrystallographically characterized. Compound 1 forms GS sheets, but in contrast to the methyl orange analogue [C(NH2)3]-[O3SC6H4N=NC6H4NMe2], these are arranged in continuously interdigitated layers as opposed to bilayers in the extended structure. The GS structure is preserved in 3 despite the loss of one NH donor in the cation, but ribbons are formed instead of sheetsin 4. Na[O3SC6H4N=NC6H4NEt2] is protonated by dilute hydrochloric acid to form the zwitterionic compound O3SC6H4NH=NC6H4NEt2·0.75H2O (5). Reaction of 4-aminoazobenzene-4'-sulfonate with a range of substituted guanidinium salts led to the formationof [C(NH2)3][O3SR'] (6), [C(NH2)2(NHMe)][O3SR'] (7), [C(NH2)2(NHEt)]2[O3SR'][O3SC6H4N=NC6H4NO2] (8) and [C(NH2)2(NMe2)][O3SR'] (9) (R' = C6H4N=NC6H4NH2). These compounds typically have more complex structures than their ethyl orangeanalogues, in part due to the presence of the additional hydrogen-bond donors. The structures of compounds 6 and 7 are based onhydrogen-bonded cylinders, with 7 containing unusual GS loops, consisting of four cations and four anions. Solid-state samples ofboth 1 and 6 react with HCl gas. X-ray powder diffraction studies reveal that 1 reacts with HCl to give 5 and [C(NH2)3]Cl asseparate phases and that this mixture reacts with NH3 gas to reform 1 together with NH4Cl. This is in contrast to observations on[C(NH2)3][O3SC6H4N=NC6H4NMe2], which reacts with HCl under the same conditions to give a product in which O3SC6H4NH=NC6H4NMe2 and [C(NH2)3]Cl are not present as separate phases.