Effects of Anodic Potential and Chloride Ion on Overall Reactivity in Electrochemical Reactors Designed for Solar-Powered Wastewater Treatment

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• 作者：Kangwoo Cho ; Yan Qu ; Daejung Kwon ; Hao Zhang ; Clément A. Cid ; Asghar Aryanfar ; Michael R. Hoffmann
• 刊名：Environmental Science & Technology
• 出版年：2014
• 出版时间：February 18, 2014
• 年：2014
• 卷：48
• 期：4
• 页码：2377-2384
• 全文大小：367K
• ISSN：1520-5851

文摘

We have investigated electrochemical treatment of real domestic wastewater coupled with simultaneous production of molecular H₂ as useful byproduct. The electrolysis cells employ multilayer semiconductor anodes with electroactive bismuth-doped TiO₂ functionalities and stainless steel cathodes. DC-powered laboratory-scale electrolysis experiments were performed under static anodic potentials (+2.2 or +3.0 V NHE) using domestic wastewater samples, with added chloride ion in variable concentrations. Greater than 95% reductions in chemical oxygen demand (COD) and ammonium ion were achieved within 6 h. In addition, we experimentally determined a decreasing overall reactivity of reactive chlorine species toward COD with an increasing chloride ion concentration under chlorine radicals (Cl路, Cl₂^{鈥?/sup>路) generation at +3.0 V NHE. The current efficiency for COD removal was 12% with the lowest specific energy consumption of 96 kWh kgCOD鈥? at the cell voltage of near 4 V in 50 mM chloride. The current efficiency and energy efficiency for H₂ generation were calculated to range from 34 to 84% and 14 to 26%, respectively. The hydrogen comprised 35 to 60% by volume of evolved gases. The efficacy of our electrolysis cell was further demonstrated by a 20 L prototype reactor totally powered by a photovoltaic (PV) panel, which was shown to eliminate COD and total coliform bacteria in less than 4 h of treatment.}