Self-Assembly Syntheses, Structural Characterization, and Luminescent Properties of Lanthanide Coordination Polymers Constructed by Three Triazole-Carboxylate Ligands
文摘
Herein, 15 lanthanide coordination complexes based on three di-, tri-, and tetra-carboxylic ligands with imidazolyl groups have been solvothermally designed, synthesized, and characterized. All the complexes exhibit high thermal stabilities and can remain stable in the open air more than 7 days. Luminescent spectra of Eu<sup>3+sup> and Tb<sup>3+sup> complexes at room temperature indicate that the three carboxylic ligands H<sub>2sub>L<sup>1sup>, H<sub>3sub>L<sup>2sup>, and H<sub>4sub>L<sup>3sup> are promising potential light sensitizers for lanthanide ions based on their suitable triplet energy levels. Luminescent lifetimes and quantum yields of these compounds were further measured and compared. The correlations between their structural features and photophysical properties are discussed in detail.