Five-Vertex Lanthanide Coordination on Surfaces: A Route to Sophisticated Nanoarchitectures and Tessellations

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• 作者：Jos茅 I. Urgel ; David Ecija ; Willi Auw盲rter ; Anthoula C. Papageorgiou ; Ari P. Seitsonen ; Saranyan Vijayaraghavan ; Sushobhan Joshi ; Sybille Fischer ; Joachim Reichert ; Johannes V. Barth
• 刊名：Journal of Physical Chemistry C
• 出版年：2014
• 出版时间：June 19, 2014
• 年：2014
• 卷：118
• 期：24
• 页码：12908-12915
• 全文大小：623K
• 年卷期：v.118,no.24(June 19, 2014)
• ISSN：1932-7455

文摘

We report a combined scanning tunneling microscopy and density functional theory study on the formation of intricate networks involving a flexible 5-fold carbonitrile鈥搇anthanide (cerium or gadolinium) coordination. By employing linear linkers equipped with terminal carbonitrile functional groups, and by tuning the local rare-earth to molecule stoichiometry, architectures evidencing high spatial complexity become manifested, including disordered islands of pentameric and nonameric supramolecules, a 2D hierarchical short-range orientational disordered network, and a 2D Archimedean snub square tessellation of the surface, which coexists with minority 2D Archimedean elongated triangular tiling motifs. The combination of both the intricate structural features and the unique properties of lanthanide elements prospects great potential in a variety of fields such as magnetism and catalysis. Furthermore, the expression of Archimedean tiling motifs based on 5-fold vertexes suggests a route to the design of self-assembled dodecagonal quasicrystals on surfaces.