The synthesis and characterization of a new tridentate amidomethylpyrrolidepyridine ligand (LigH<sub>2sub>) and of the corresponding LigZr(NMe<sub>2sub>)<sub>2sub> complex (1) are described. Characterization of 1 by single-crystal X-ray diffraction analysis showed a slightly distorted square-pyramidal geometry. Variable-temperature NMR analysis suggested that 1 adopts a C<sub>ssub>-symmetric structure in solution. Complex 1 in combination with Al<sup>isup>Bu<sub>2sub>H and methylalumoxane afforded a highly active single-site catalyst for the polymerization of ethylene and propene, producing ultrahigh molecular weight linear polyethylene and isotactic polypropylene via an “enantiomorphic sites” mechanism of steric control.