Thermal Stability Improvement of exo-Tetrahydrodicyclopentadiene by 1,2,3,4-Tetrahydroquinoxaline: Mechanism and Kinetics

详细信息    查看全文

• 作者：Sun Hee Park ; Cheong Hoon Kwon ; Joongyeon Kim ; Jeong Hwan Chun ; Wonkeun Chung ; Byung-Hee Chun ; Jeong Sik Han ; Byung Hun Jeong ; Hogyu Han ; Sung Hyun Kim
• 刊名：The Journal of Physical Chemistry C
• 出版年：2013
• 出版时间：April 18, 2013
• 年：2013
• 卷：117
• 期：15
• 页码：7399-7407
• 全文大小：454K
• 年卷期：v.117,no.15(April 18, 2013)
• ISSN：1932-7455

文摘

We investigated the thermal stability of exo-tetrahydrodicyclopentadiene (exo-THDCP, C₁₀H₁₆) in the absence and presence of three additives, 3,4-dihydro-2H-1,4-benzoxazine (Benzox), 1,2,3,4-tetrahydroquinoline (THQ), and 1,2,3,4-tetrahydroquinoxaline (THQox), which act as hydrogen donors (H donors). Conversion of exo-THDCP was slowed in the presence of the H donor. The order of the H-donor effects on the decrease in the conversion of exo-THDCP was Benzox THQ < THQox. The H-donor-induced decrease in the conversion of exo-THDCP was smaller at higher temperature. In addition, the H-donor-induced decrease in the rate of <C₁₀ product formation was smaller than that of 鈮₁₀. We proposed the mechanism for the thermal decomposition of exo-THDCP in the presence of the H donor. The proposed mechanism explains the unusual thermal decomposition kinetics of exo-THDCP and H donors: (i) exo-THDCP does not follow first-order kinetics and (ii) THQ and THQox show the S-shaped concentration鈥搕ime curves. We also proposed the mechanism for H donations by Benzox, THQ, and THQox. The proposed mechanism elucidates that THQox performs faster H donation than THQ and has higher thermal stability than Benzox, which accounts for the more effective thermal stability improvement of exo-THDCP by THQox compared to THQ and Benzox.