Supramolecular Hexagon and Chain Coordination Polymer Containing the MoO22+ Core: Structural Transformation in the Solid State

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• 作者：Vis虒nja Vrdoljak ; Biserka Prugovec虒ki ; Dubravka Matkovic虂-C虒alogovic虂 ; Jana Pisk ; Renata Dreos ; Patrizia Siega
• 刊名：Crystal Growth & Design
• 出版年：2011
• 出版时间：April 6, 2011
• 年：2011
• 卷：11
• 期：4
• 页码：1244-1252
• 全文大小：1027K
• 年卷期：v.11,no.4(April 6, 2011)
• ISSN：1528-7505

文摘

The reaction of [MoO₂(acac)₂] (where acac = acetylacetonate ligand) with the salicylaldehyde isonicotinyl hydrazonate ligand (SIH^{2鈭?/sup>) yielded a zigzag chain polymer [MoO₂(SIH)]_n (1), an interwoven hexagon [MoO₂(SIH)]₆ (2), or the mononuclear complexes [MoO₂(SIH)(C₂H₅OH)] (3EtOH) and [MoO₂(SIH)(C₃H₇OH)] (3PrOH). Diversity in the formation of dioxomolybdenum(VI) compounds illustrates their sensitivity to the reaction conditions. Crystal and molecular structures of all of the investigated molybdenum(VI) compounds were determined by the single crystal X-ray diffraction method. Solid-state reactions lead to the transformation of the supramolecular hexagon or the mononuclear complexes into the chain coordination polymer. These thermally induced conversions were characterized by the X-ray powder diffraction method. All of the investigated compounds were further characterized by elemental analysis, thermogravimetric analyses, Fourier transform infrared (FT-IR), and NMR spectroscopy.}