The First Nitro-Substituted Heteroscorpionate Ligand
详细信息 查看全文
- 作者：Maura Pellei ; Franco Benetollo ; Giancarlo Gioia Lobbia ; Simone Alidori ; and Carlo Santini
- 刊名：Inorganic Chemistry
- 出版年：2005
- 出版时间：February 21, 2005
- 年：2005
- 卷：44
- 期：4
- 页码：846 - 848
- 全文大小：67K
- 年卷期：v.44,no.4(February 21, 2005)
- ISSN：1520-510X
文摘
The new dihydridobis(3-nitro-1,2,4-triazolyl)borate ligand,[H2B(tzNO2)2]-, has been synthesized in dimethylacetamide solution,using 3-nitro-1,2,4-triazole and KBH4 through careful temperaturecontrol, and characterized as its potassium salt. The zinc(II) andcadmium(II) complexes, {M[H2B(tzNO2)2]Cl(H2O)2}, have beenprepared by metathesis of [H2B(tzNO2)2]K with ZnCl2 and CdCl2,respectively. The complexes likely contain a metal core in whichthe ligand is coordinated to the metal ions in the 
2-N,N' or 4-N,N',O,O' fashion. A single-crystal structural characterization isreported for the potassium dihydrobis(3-nitro-1,2,4-triazolyl)borate.The potassium salt is polymeric and shows several K···N andK···O interactions.
2-N,N' or 4-N,N',O,O' fashion. A single-crystal structural characterization isreported for the potassium dihydrobis(3-nitro-1,2,4-triazolyl)borate.The potassium salt is polymeric and shows several K···N andK···O interactions.