Confirmation of the Origins of Panchromatic Spectra in Squaraine Thin Films Targeted for Organic Photovoltaic Devices

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• 作者：Nicholas J. Hestand ; Chenyu Zheng ; Anirudh Raju Penmetcha ; Brandon Cona ; Jeremy A. Cody ; Frank C. Spano ; Christopher J. Collison
• 刊名：Journal of Physical Chemistry C
• 出版年：2015
• 出版时间：August 20, 2015
• 年：2015
• 卷：119
• 期：33
• 页码：18964-18974
• 全文大小：533K
• ISSN：1932-7455

文摘

Squaraines offer significant potential for organic photovoltaics because of their broad absorbance and high extinction coefficients as well as their expected use as mechanistic probes in such devices. In this work steps are taken to develop a comprehensive understanding of the excited-state properties of squaraines on the basis of their molecular structure and the resulting solid-state packing. Accurate assignments of the absorption spectral peaks are made on the basis of an essential states model, expanded to include intermolecular charge transfer (ICT). A comparison of simulated spectra with spectra for two symmetric squaraine derivatives confirms that ICT has a major influence on the optical and electronic properties of squaraine aggregates, fully accounting for the origin of the strong panchromaticity of these systems.