Comprehensive Study of the Impact of Steam on Polyethyleneimine on Silica for CO2 Capture

详细信息    查看全文

• 作者：Sonia Hammache ; James S. Hoffman ; McMahan L. Gray ; Daniel J. Fauth ; Bret H. Howard ; Henry W. Pennline
• 刊名：Energy & Fuels
• 出版年：2013
• 出版时间：November 21, 2013
• 年：2013
• 卷：27
• 期：11
• 页码：6899-6905
• 全文大小：391K
• 年卷期：v.27,no.11(November 21, 2013)
• ISSN：1520-5029

文摘

An amine sorbent, prepared by impregnation of polyethyleneimine on silica, was tested for steam stability. The stability of the sorbent was investigated in a fixed bed reactor using multiple steam cycles of 90 vol % H₂O/He at 105 掳C, and the gas effluent was monitored with a mass spectrometer. CO₂ uptake of sorbent was found to decrease with repeated exposure to steam. Characterization of the spent sorbent using N₂ physisorption, SEM, and thermogravimetric analysis (TGA) showed that the decrease in CO₂ loading can possibly be attributed to a reagglomeration of the amine in the pores of the silica. No support effect was found in this study. The commercial SiO₂ used, Cariact G10, was found to be stable under the conditions used. While it was found that subjecting the sorbent to several steam cycles decreased its CO₂ uptake, a continuous exposure of the sorbent to steam did not have a significant performance impact. A silanated sorbent, consisting of a mixture of PEI and aminopropyl-triethoxysilane on SiO₂ support, was also investigated for steam stability. Similarly to the nonsilanated sorbent, the CO₂ loading of this sorbent decreased upon steam exposure, although a mechanism for this change has not been postulated at this time.