Chemical Insights from EPR Spectra of Organometallic Radicals and Radical Ions
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- 作者：Anne L. Rieger and Philip H. Rieger
- 刊名：Organometallics
- 出版年：2004
- 出版时间：January 19, 2004
- 年：2004
- 卷：23
- 期：2
- 页码：154 - 162
- 全文大小：228K
- 年卷期：v.23,no.2(January 19, 2004)
- ISSN：1520-6041
文摘
A review of applications of electron paramagnetic resonance (EPR) to organometallics isgiven, covering about 35 years of the authors' work. The review includes applications wherethe conclusions are mainly a picture of electronic structure, though often knowledge of thesingly occupied molecular orbital (SOMO) has implications for molecular structure. Includedin the review are discussions of addition of a second phosphite ligand to [Co{S2C2(CF3)2}P(OMe)3] and a unique example of electronic isomerism (summarized on the cover).