Structure-Directing Self-Assembly, Structures and Characterization of Four d0-Transition Metal Oxide/Fluoride Compounds Constructed with Imidazole/1-Methylimidazole/1-Vinylimidazole and Cop

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• 作者：Yi-Ping Tong ; Guo-Tian Luo ; Jin Zhen ; You Shen ; Hui-Ru Liu
• 刊名：Crystal Growth & Design
• 出版年：2013
• 出版时间：February 6, 2013
• 年：2013
• 卷：13
• 期：2
• 页码：446-454
• 全文大小：743K
• 年卷期：v.13,no.2(February 6, 2013)
• ISSN：1528-7505

文摘

Four d⁰ transition metal oxide/fluoride compounds of V(V), Mo(VI), and Ti(IV), with the 鈥?D layer鈥? 鈥?D zigzag chain鈥? 鈥?D linear chain鈥? and 鈥?D cluster鈥?structures, have been hydrothermally synthesized, by the structure-directing self-assembly of Meimi/Viimi/imi ligands, and other transition metal Zn(II)/Cd(II) ions. The structure-directing property of d⁰ transition metal oxide/fluoride anions is responsible for the tunable syntheses of novel inorganic solids with structural diversities, while the distortion of the d⁰ transition metal oxide/fluoride polyhedrons, owing to the second-order Jahn鈥揟eller (SOJT) effect, is the key to engineering the structure-directing property.