Direct Synthesis of Mesostructured Lamellar Molybdenum Disulfides Using a Molten Neutral n-Alkylamine as the Solvent and Template

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• 作者：Britt A. Vanchura ; Pingang He ; Valentyn Antochshuk ; Mietek Jaroniec ; Amy Ferryman ; Dmytro Barbash ; Julia E. Fulghum ; and Songping D. Huang
• 刊名：Journal of the American Chemical Society
• 出版年：2002
• 出版时间：October 16, 2002
• 年：2002
• 卷：124
• 期：41
• 页码：12090 - 12091
• 全文大小：71K
• 年卷期：v.124,no.41(October 16, 2002)
• ISSN：1520-5126

文摘

A series of novel mesostructured lamellar molybdenum disulfides with the d spacings from 17 to 30 Å can be prepared by the reaction of Mo(CO)₆ with elemental sulfur using a molten n-alkylamine as the solvent as well as the template at 140 C. Such intercalated phases can be transformed into mesoporous molybdenum disulfides by slow thermal treatments at 200 C.