Ultrahigh Sensitivity of Au/1D 伪-Fe2O3 to Acetone and the Sensing Mechanism

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• 作者：Poernomo Gunawan ; Lin Mei ; Jaclyn Teo ; Jianmin Ma ; James Highfield ; Qiuhong Li ; Ziyi Zhong
• 刊名：Langmuir
• 出版年：2012
• 出版时间：October 2, 2012
• 年：2012
• 卷：28
• 期：39
• 页码：14090-14099
• 全文大小：830K
• 年卷期：v.28,no.39(October 2, 2012)
• ISSN：1520-5827

文摘

Hematite (伪-Fe₂O₃) is a nontoxic, stable, versatile material that is widely used in catalysis and sensors. Its functionality in sensing organic molecules such as acetone is of great interest because it can result in potential medical applications. In this report, microwave irradiation is applied in the preparation of one-dimensional (1D) 伪-FeOOH, thereby simplifying our previous hydrothermal method and reducing the reaction time to just a few minutes. Upon calcination, the sample was converted to porous 伪-Fe₂O₃ nanorods, which were then decorated homogeneously by fine Au particles, yielding Au/1D 伪-Fe₂O₃ at nominally 3 wt % Au. After calcination, the sample was tested as a potential sensor for acetone in the parts per million range and compared to a similarly loaded Pt sample and the pure 1D 伪-Fe₂O₃ support. Gold addition results in a much enhanced response whereas Pt confers little or no improvement. From tests on acetone in the 1鈥?00 ppm range in humid air, Au/1D 伪-Fe₂O₃ has a fast response, short recovery time, and an almost linear response to the acetone concentration. The optimum working temperature was found to be 270 掳C, which was judged to be a compromise between the thermal activation of lattice oxygen in hematite and the propensity for acetone adsorption. The surface reaction was investigated by diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS), and a possible sensing mechanism is proposed. The presence of Au nanoparticles is believed to promote the dissociation of molecular oxygen better in replenishing O vacancies, thereby increasing the instantaneous supply of lattice oxygen to the oxidation of acetone (to H₂O and CO₂), which proceeds through an adsorbed acetate intermediate. This work contributes to the development of next-generation sensors, which offer ultrahigh detection capabilities for organic molecules.