Palladium-Catalyzed Desulfitative Arylation by C鈥揙 Bond Cleavage of Aryl Triflates with Sodium Arylsulfinates

详细信息    查看全文

• 作者：Chao Zhou ; Qingjiang Liu ; Yaming Li ; Rong Zhang ; Xinmei Fu ; Chunying Duan
• 刊名：The Journal of Organic Chemistry
• 出版年：2012
• 出版时间：November 16, 2012
• 年：2012
• 卷：77
• 期：22
• 页码：10468-10472
• 全文大小：278K
• 年卷期：v.77,no.22(November 16, 2012)
• ISSN：1520-6904

文摘

An efficient Pd-catalyzed desulfitative coupling reaction of sodium arylsulfinates as arylation reagents by C鈥揙 bond cleavage of aryl triflates was developed. With only 2 mol % of Pd(OAc)₂ as catalyst and XPhos as ligand, the reaction proceeded well for a range of substrates.