Ru(II)-Catalyzed Direct C(sp2)–H Activation/Selenylation of Arenes with Selenyl Chlorides

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• 作者：Shiqi Shu ; Zhoulong Fan ; Qizheng Yao ; Ao Zhang
• 刊名：Journal of Organic Chemistry
• 出版年：2016
• 出版时间：July 1, 2016
• 年：2016
• 卷：81
• 期：13
• 页码：5263-5269
• 全文大小：474K
• 年卷期：0
• ISSN：1520-6904

文摘

A new ruthenium catalytic system was developed for the construction of a C(sp²)–Se bond with the assistance of directing groups. This protocol features mild reaction conditions, wider substrate scope, and convenient late-stage selenylation of bioactive molecules.