Multigram Scale Syntheses of First and Second Generation of Trifluoromethanesulfenamide Reagents

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• 作者：Quentin Glenadel ; Sébastien Alazet ; François Baert ; Thierry Billard
• 刊名：Organic Process Research & Development
• 出版年：2016
• 出版时间：May 20, 2016
• 年：2016
• 卷：20
• 期：5
• 页码：960-964
• 全文大小：265K
• 年卷期：0
• ISSN：1520-586X

文摘

Trifluoromethanesulfenamide reagents constitute a family of very efficient reagents to trifluoromethylthiolate various molecules. Optimized syntheses have been developed to easily obtain, in a reproducible manner, large quantities of these reagents, with good overall yields. Up to 84 g have already been obtained, at a reasonable cost.