Polymerization of Racemic 尾-Butyrolactone Using Gold Catalysts: A Simple Access to Biodegradable Polymers
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- 作者：Emilie Brule虂 ; Sylvain Gaillard ; Marie-Noe虉lle Rager ; Thierry Roisnel ; Vincent Gue虂rineau ; Steven P. Nolan ; Christophe M. Thomas
- 刊名：Organometallics
- 出版年：2011
- 出版时间：May 23, 2011
- 年：2011
- 卷：30
- 期：10
- 页码：2650-2653
- 全文大小：732K
- 年卷期：v.30,no.10(May 23, 2011)
- ISSN：1520-6041
文摘
Novel gold(I) complexes containing N-heterocyclic carbene ligands have been synthesized and fully characterized. The resulting mononuclear gold complexes act as active initiators in the polymerization of rac-尾-butyrolactone under solvent-free conditions to provide the corresponding biodegradable poly(3-hydroxybutyrate).