NHC Catalyzed Transformation of Aromatic Aldehydes to Acids by Carbon Dioxide: An Unexpected Reaction

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• 作者：Vijay Nair ; Vimal Varghese ; Rony Rajan Paul ; Anu Jose ; C. R. Sinu ; Rajeev S. Menon
• 刊名：Organic Letters
• 出版年：2010
• 出版时间：June 4, 2010
• 年：2010
• 卷：12
• 期：11
• 页码：2653-2655
• 全文大小：135K
• 年卷期：v.12,no.11(June 4, 2010)
• ISSN：1523-7052

文摘

A facile NHC-mediated reaction of aromatic aldehydes with carbon dioxide leading to carboxylic acids is described. The present protocol is mechanistically important, and it can serve as a tool for the sequestration of carbon dioxide.