Synthesis and Characterization of Phosphine-Functionalized Metal鈥揙rganic Frameworks Based on MOF-5 and MIL-101 Topologies
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- 作者：Flavien L. Morel ; Marco Ranocchiari ; Jeroen A. van Bokhoven
- 刊名：Industrial & Engineering Chemistry Research
- 出版年：2014
- 出版时间：June 4, 2014
- 年：2014
- 卷：53
- 期：22
- 页码：9120-9127
- 全文大小：373K
- 年卷期：v.53,no.22(June 4, 2014)
- ISSN：1520-5045
文摘
Phosphine metal鈥搊rganic frameworks (P-MOFs) are an emerging class of coordination polymers that provide novel opportunities for metal鈥搒upported catalysis as solid ligands. Here, we present the synthesis and characterization of three novel P-MOFs based on a (diphenylphosphino)terephthalic acid linker. We targeted the structures of MOF-5, MIL-101(Cr), and MIL-101(Al)-NH2 to produce materials with partial diphenylphosphine substitution, which were crystalline and highly porous.