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• 作者：Dennis Troegel ; Frank Mller ; Christian Burschka ; Reinhold Tacke
• 刊名：Organometallics
• 出版年：2009
• 出版时间：October 12, 2009
• 年：2009
• 卷：28
• 期：19
• 页码：5765-5770
• 全文大小：780K
• 年卷期：v.28,no.19(October 12, 2009)
• ISSN：1520-6041

文摘

A series of novel trifunctional tetraorganylsilanes of the general formula types MeSi(CH₂X)₃ (X = I (2), OAc (3), OH (4), Br (5), (4-methylphenyl)sulfonyloxy (6), phthalimido (7), NH₂·HBr (8·3HBr)), MeSi(CH₂X)₂CH₂X′ (X = SH, X′ = OH (9); X = Cl, X′ = OAc (11); X = SAc, X′ = OAc (12)), and MeSi(CH₂X)(CH₂X′)CH₂X′′ (X = Cl, X′ = OAc, X′′ = SAc (rac-13); X = phthalimido, X′ = OAc, X′′ = SAc (rac-14); X = N₃, X′ = OAc, X′′ = SAc (rac-15)) was synthesized, starting from MeSi(CH₂Cl)₃ (1). All the compounds synthesized was characterized by elemental analyses (C, H, N, S) and NMR studies (¹H, ¹³C, ¹⁵N (rac-15 only), ²⁹Si). In addition, compounds 4 and 6 were structurally characterized by single-crystal X-ray diffraction. The title compounds are claimed to be versatile starting materials for the synthesis of a variety of novel C-functional organosilicon compounds.