Boron-Containing Monopyrrolo-Annelated Tetra thiafulvalene Compounds: Synthesis and Absorption Spectral/Electrochemical Responsiveness toward Fluoride Ion
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- 作者：Jing Li ; Guanxin Zhang ; Deqing Zhang ; Renhui Zheng ; Qiang Shi ; Daoben Zhu
- 刊名：Journal of Organic Chemistry
- 出版年：2010
- 出版时间：August 6, 2010
- 年：2010
- 卷：75
- 期：15
- 页码：5330-5333
- 全文大小：807K
- 年卷期：v.75,no.15(August 6, 2010)
- ISSN：1520-6904
文摘
Two new boron-based conjugated compounds 1 and 2 containing one and three monopyrrolo-annelated tetrathiafulvalene (TTF) unit(s) were synthesized and characterized. They exhibit typical ICT absorptions which can be modulated after addition of fluoride ion. In addition, the oxidation potentials of 1 and 2 are shifted to low potential region in the presence of fluoride ion. Such absorption spectral and electrochemical responsiveness of 1 and 2 toward fluoride ion is due to the binding of the boron units with fluoride ion.